Yeu, Taewhan, Trung V. Nguyen, and Ralph E. White. 1988. “A Mathematical Model for Predicting Cyclic Voltammograms of Electronically Conductive Polypyrrole”. Journal of The Electrochemical Society 135 (8): 1971-76.
Abstract
Polypyrrole is an attractive polymer for use as a high-energy-density secondary battery because of its potential as an inexpensive, lightweight, and noncorrosive electrode material. A mathematical model to simulate cyclic voltammograms for polypyrrole is presented. The model is for a conductive porous electrode film on a rotating disk electrode (RDE) and is used to predict the spatial and time dependence of concentration, overpotential, and stored charge profiles within a polypyrrole film. The model includes both faradic and capacitance charge components in the total current density expression.
Last updated on 09/07/2023