Maximizing the Life of a Lithium-Ion Cell by Optimization of Charging Rates

Using a dynamic optimization method, the optimum charge currents as a function of cycle number during cycling for the lithium-ion cell are obtained. A single particle physics-based model, which includes capacity fade, was applied to simulate the cell performance under low earth-orbit (LEO) cycling conditions. Useful cell life is defined as the number of cycles before the end of discharge voltage drops below 3.0 V or the cell discharge capacity becomes less than 20% of the original discharge capacity. The simulated useful cell life can be increased by ∼29.28% by varying the charge current. © 2010 The Electrochemical Society.