Semianalytical method of solution for solid phase diffusion in lithium ion battery electrodes: Variable diffusion coefficient

A semianalytical methodology based on the integral transform technique is proposed to solve the diffusion equation with concentration dependent diffusion coefficient in a spherical intercalation electrode particle. The method makes use of an integral transform pair to transform the nonlinear partial differential equation into a set of ordinary differential equations, which is solved with less computational efforts. A general solution procedure is presented and two illustrative examples are used to demonstrate the usefulness of this method for modeling of diffusion process in lithium ion battery electrode. The solutions obtained using the method presented in this study are compared to the numerical solutions. © 2010 Elsevier B.V.